Synthesis of Zeolite-A Pellets from Bangka Kaolin and Its Application in Ethanol Dehydration

Maria Ulfah; Pasymi; Amelia Amir; M Iqbal; Nandita Hadi

doi:10.31938/jsn.v15i2.776

Synthesis of Zeolite-A Pellets from Bangka Kaolin and Its Application in Ethanol Dehydration

Authors

Maria Ulfah Universitas Bung Hatta
Pasymi Universitas Bung Hatta
Amelia Amir Universitas Bung Hatta
M Iqbal Universitas Bung Hatta
Nandita Hadi Universitas Bung Hatta

DOI:

https://doi.org/10.31938/jsn.v15i2.776

Keywords:

Kaolin Bangka, Zeolite A pellet, Ethanol

Abstract

Indonesia has abundant natural clay resources, including kaolin. In the Bangka Belitung Province, the kaolin reserves are estimated at 376,687,532 tons with identified reserve reaching 5,990,630 tons. The primary mineral constituents of kaolin are alumina and silica, which are essential raw materials for zeolite synthesis. Additionally, kaolin is widely utilized as a binder in various industrial applications. The research aimed to evaluated the potential of kaolin as a source of alumina and silica, as well as its effectiveness as a binder. This study investigated the influenced of calcination temperature and the composition of reactants (metakaolin, NaOH, and water) on the the performance of zeolite A pellets. The general process for yielding zeolite A pellets involved three main stages: transforming kaolin to metakaolin; preparing zeolite A powder and forming the pellets by mixing the synthesized zeolite A powder with calcined kaolin (metakaolin). In this study, kaolin was calcined at two temperatures at 570°C and 670°C, to produce metakaolin. The variables adjusted in the production of zeolite. The molar ratios of H₂O to Na₂O used in zeolite synthesis were varied at 37, 40, and 43, while the molar ratio of SiO₂ to Al₂O₃ was maintained at 2.4, based on the chemical composition of the kaolin. Additionally, the Na₂O to SiO₂ ratio was kept constant at 2.5. X-ray diffraction (XRD) analysis confirmed that the synthesized material was zeolite A. The performance of the developed zeolite A pellets was found to be comparable to that of commercial catalysts. The optimal synthesis conditions were achieved with an H₂O/Na₂O ratio of 43 and kaolin calcined at 670°C. These results demonstrate that Bangka kaolin serves considerable potential for use both as a source of alumina and silica, and as a binder.

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References

Abdullah, A. H., Zulkefli, N. N., Abd Aziz, A. S., & Mat, R. (2016). Synthesis of zeolite Na-A from local kaolin for bioethanol purification. Indian Journal of Science and Technology, 9(9). https://doi.org/10.17485/ijst/2016/v9i9/88726

Abdullahi, T., Harun, Z., & Othman, M. H. D. (2017). A review on sustainable synthesis of zeolite from kaolinite resources via hydrothermal process. Advanced Powder Technology, 28(8), 1827–1840. https://doi.org/10.1016/j.apt.2017.04.028

Ayele, L., Pérez-Pariente, J., Chebude, Y., & Díaz, I. (2015). Synthesis of zeolite A from Ethiopian kaolin. Microporous and Mesoporous Materials, 215, 29–36. https://doi.org/10.1016/j.micromeso.2015.05.022

Eluwa, V. C., Obasa, P. A., Esther, M., & Igbonekwu, C. A. (2024). Synthesis and Characterization of Zeolite A from Aloji Kaolin Via Hydrothermal Method. Journal of Materials Science Research and Reviews Volume, 7(4), 592–601.

Hafeez Azhar, F., Harun, Z., Farah, W. N., Hanafi, A., Sazali, N., Hussin, R., Kamdi, Z., Ainuddin, A. R., Yunos, M. Z., & Ismail, A. (2024). Zeolite Synthesis from Natural Kaolin: The Effect of Metakaolin Heating and Transformation. 5(1), 75–81. https://publisher.uthm.edu.my/ojs/index.php/emait

He, Y., Tang, S., Yin, S., & Li, S. (2021). Research progress on green synthesis of various high-purity zeolites from natural material-kaolin. Journal of Cleaner Production, 306, 127248. https://doi.org/10.1016/j.jclepro.2021.127248

Inglezakis, V. J., Balsamo, M., & Montagnaro, F. (2020). Liquid-Solid Mass Transfer in Adsorption Systems - An Overlooked Resistance? Industrial and Engineering Chemistry Research, 59(50), 22007–22016. https://doi.org/10.1021/acs.iecr.0c05032

Karimi, S., Tavakkoli Yaraki, M., & Karri, R. R. (2019). A comprehensive review of the adsorption mechanisms and factors influencing the adsorption process from the perspective of bioethanol dehydration. Renewable and Sustainable Energy Reviews, 107(July 2018), 535–553. https://doi.org/10.1016/j.rser.2019.03.025

Kirdeciler, S. K., & Akata, B. (2020). One pot fusion route for the synthesis of zeolite 4A using kaolin. Advanced Powder Technology, 31(10), 4336–4343. https://doi.org/10.1016/j.apt.2020.09.012

Król, M., & Ro?ek, P. (2018). The effect of calcination temperature on metakaolin structure for the synthesis of zeolites. Clay Minerals, 53(4), 657–663. https://doi.org/10.1180/clm.2018.49

Li, T., Wang, S., Gao, J., Wang, R., Gao, G., Ren, G., Na, S., Hong, M., & Yang, S. (2024). Spherical Binderless 4A/5A Zeolite Assemblies: Synthesis, Characterization, and Adsorbent Applications. Molecules, 29(7), 1–15. https://doi.org/10.3390/molecules29071432

Lim, W. R., Lee, C. H., & Hamm, S. Y. (2021). Synthesis and characteristics of Na-A zeolite from natural kaolin in Korea. Materials Chemistry and Physics, 261(January), 124230. https://doi.org/10.1016/j.matchemphys.2021.124230

Madani, A., Aznar, A., Sanz, J., & Serratosa, J. M. (1990). 29Si and 27Al NMR study of zeolite formation from alkali-leached kaolinites. Influence of thermal preactivation. Journal of Physical Chemistry, 94(2), 760–765. https://doi.org/10.1021/j100365a046

Maia, A. Á. B., Dias, R. N., Angélica, R. S., & Neves, R. F. (2019). Influence of an aging step on the synthesis of zeolite NaA from Brazilian Amazon kaolin waste. Journal of Materials Research and Technology, 8(3), 2924–2929. https://doi.org/10.1016/j.jmrt.2019.02.021

Mgbemere, H. E., Lawal, G. I., Ekpe, I. C., & Chaudhary, A. L. (2018). Synthesis of zeolite-A using kaolin samples from Darazo, Bauchi state and Ajebo, Ogun state in Nigeria. Nigerian Journal of Technology, 37(1), 87. https://doi.org/10.4314/njt.v37i1.12

Milton, R.M., B. N. . (1953). Molecular Sieve Adsorbents. U.S. Patent 2882244, 2882244.

Nikolopoulos, N., Wickramasinghe, A., Whiting, G. T., & Weckhuysen, B. M. (2022). Alumina binder effects on the hydrothermal stability of shaped zeolite-based catalyst bodies. Catalysis Science and Technology, 13(3), 862–873. https://doi.org/10.1039/d2cy01894b

Nozemack, R.J., W., C.C, & Schwonke, J. . (1983). Binderless Zeolite Extruded and Method of Producing.

Nurhidayati, Hasfianti F.E., W. K. (2020). Kajian Teknoekonomi Kaolin Belitung Sebagai Bahan Substitusi Impor Pada Produksi Fiber Cement Board. Jurnal Keramik Dan Gelas Indonesia, 29(Desember), 152–164.

Sari, M. E. F., Suprapto, & Prasetyoko, D. (2018). Direct synthesis of sodalite from kaolin: The influence of alkalinity. Indonesian Journal of Chemistry, 18(4), 607–613. https://doi.org/10.22146/ijc.25191

Sazali, N., & Harun, Z. (2022). One Shot of the Hydrothermal Route for the Synthesis of Zeolite LTA Using Kaolin. Journal of Inorganic and Organometallic Polymers and Materials, 32(9), 3508–3520. https://doi.org/10.1007/s10904-022-02369-y

Somderam, S., Abd Aziz, A. S., Abdullah, A. H., & Mat, R. (2019). Characterisation of NAA zeolite made from Malaysian kaolin. Chemical Engineering Transactions, 72(February 2018), 325–330. https://doi.org/10.3303/CET1972055

Ulfah M., Praputri E., Firdaus, Muchtiar Y., and B. (2023). Synthesis and characterization of a zeolite pellet using natural Kaolinite clays from Indonesia as binder and their application in dehydration ethanol , AIP Conference Proceedings 2691, 050002 (2023) Https://Doi.Org/10.1063/5.0115184. https://doi.org/10.1016/0144-2449(84)90039-3